Iron Man (real nameAnthony "Tony" Stark) is the famous owner of Stark Industries and a member of the Avengers. He has the most non heroes for hire appearances in the show. He has 7 apperences.
In Great Power and Great Responsibility, Iron Man, alongside Thor and Captain America, first appears as images in Spider-Man's brain when Nick Fury tells him he can be the next Avenger.
In Flight of the Iron Spider his first full appearance, Nick Fury tells Spider-Man to stay away from Iron Man, as Iron Man serves as an idol to Spider-Man. In turn, Iron Man likes Spider-Man's style and even invited him to Stark Towers. During this visit, Iron Man give's Spider-Man the Iron Spider Armor.
Tony may be bossy and always bragging about himself sometimes, but he also knows how to sacrifice himself and help others, such as telling the Living Laser to stop controlling the Iron Spider armor and just control him instead.
Powers and Abilities
Repulsor Rays: As Iron Man, Tony can shoot powerful rays out of his palms.
Arc Reactor: As Iron Man, Tony can shoot a very powerful beam out of his chest more powerful than his Repulsor Rays.
'Missiles': As Iron Man, Tony can shoot multiple missles at the same time out of his armor.
J.A.R.V.I.S.: - Just A Rather Very Intelligent System. Is Tony's computer which he can order to do several things to the armor. J.A.R.V.I.S also informs Tony when there is danger in the armor.
Flight: As Iron Man, Tony can fly around with his armor as means of transportation as fast as possible.
Enhanced Durability: Tony's armor can take a lot of damage.
Enhanced Strength: As Iron Man, Tony can lift many tons.